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Polymer Processing

 

Abstract

Polymeric materials – usually called plastics in popular usage – are ubiquitous in modern life. Applications range from film to textile fibres to complex electronic interconnects to structural units in automobiles and aeroplanes to orthopaedic implants. Polymers are giant molecules, consisting of hundreds/thousands of connected monomers, or primary chemical groups; a polyethene molecule, for example, is merely a chain of covalently bonded carbon atoms, each carbon-containing two hydrogen atoms to make the four valence sites.

The polyethene used to fabricate plastic movie commonly has a typical molecular weight (referred to as the number-normal molecular weight, denoted Mn) of about 29,000, or about 2,000 —CH2— items, every with a molecular weight of 14. The logo “—” on every aspect of the CH2 denotes a single covalent bond with the adjacent carbon atom.

The monomer is ethylene, CH2 ——CH2, where “——” denotes a double bond among the carbons that open for the period of the polymerisation manner, and a single me is —CH2—CH2—. For that reason, the molecular weight of the monomer is 28, and the measure of polymerisation is ready 1,000.) The extremely-high molecular weight polyethene used in artificial hips and different prosthetic contraptions has about 36,000 —CH2— units. Polystyrene can also be a chain of covalently bonded carbon atoms, but one hydrogen on each 2nd carbon substituted with a phenyl (benzene) ring. Two or more monomers might be polymerised together to type a copolymer, showing on the chain in either a regular or intermittent sequence.

Polymers are often contained additives and blended to affect the properties of the solid phase; high-impact polystyrene, for example, is a blend in which particles of a rubbery polymer, typically polybutadiene or a styrene-butadiene copolymer, are dispersed in polystyrene. There are such type of polymer composites used in moulding applications contain solid fillers, such as calcium carbonate particles, glass fibres, or even nanoscale fillers like exfoliated clays or carbon nanotubes.

The polymer manufacturer, starting from raw materials like natural gas and other low molecular weight chemicals, produces the polymer – say polyethene – as a powder or in the form of chips or flakes, which can be almost always transformed (densified) into pellets by way of extrusion.

This resin needs to be processed to produce the preferred product – a moulded section, for example. Most processing takes place within the liquid state. The adhesive required first to be melted, then conveyed via some steps to form an object of the favoured shape, and in the end solidified once more. A polymer pipe, for instance, is produced by consistently extruding the molten polymer through an annular die and then cooling it speedily to preserve the form. An injection-moulded section defined with the aid of forcing the molten polymer into a mould of the desired method, the place the polymer cools unless it has solidified, after which the body completed, the phase removed, and the process reproduced.

Extrusion

Extrusion is the most essential and most extensively used unit operation in softening processing. An extruder is a gadget that pressurises a soften to drive it through a shaping die or another unit. A ram extruder, for example, is purely a piston that pushes a soften from a cylinder by way of a die. We’re usually involved with steady extrusion over long durations of time, wherein case a ram, which ought to function in a semi-batch mode (i.E., the cylinder have to refilled periodically), shouldn’t be proper. The most long-established gadget for continuous extrusion is the only-screw extruder.

The one-screw extruder is similar to the meat grinder that used to be once a fixture in kitchens. In a meat grinder, chunks of meat positioned in a hopper and fall onto a rotating Archimedes screw. The beef is compressed and carried ahead by way of the screw flights except it is pressured via a perforated plate, producing the strands that makeup “floor” meat.

The best characteristics is here, which we not often suppose approximately inside the context of a meat grinder, is that the beef enters at atmospheric strain and is compelled with the aid of manner of the perforated plate to emerge at atmospheric tension; subsequently, the call for have to grow from the hopper to the upstream side of the platen order to provide the pressure essential to push the meat thru the plate. We are familiar with thinking regarding pressure drop in float situations. Similarly, in a screw extruder the polymer, inside the form of flakes, chips, or pellets, is fed via the hopper onto the screw, where melting takes the state of affairs because of frictional and conductive heating and might be moreover deformation heating of the softening sturdy. The polymer is conveyed forward through the pin, fitting utterly molten by the point it reaches the metering component. Strain builds up inside the go with the flow direction till the give up of the screw, the place the polymer is compelled via a shaping die. The pressure drop by the manner of the die needs to same the strain buildup along the pin.

 

 

 

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